Atmospheric Chemistry and Physics (Feb 2009)

A global stratospheric bromine monoxide climatology based on the BASCOE chemical transport model

  • N. Theys,
  • M. Van Roozendael,
  • Q. Errera,
  • F. Hendrick,
  • F. Daerden,
  • S. Chabrillat,
  • M. Dorf,
  • K. Pfeilsticker,
  • A. Rozanov,
  • W. Lotz,
  • J. P. Burrows,
  • J.-C. Lambert,
  • F. Goutail,
  • H. K. Roscoe,
  • M. De Mazière

Journal volume & issue
Vol. 9, no. 3
pp. 831 – 848

Abstract

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A new climatology of stratospheric BrO profiles based on a parameterization using dynamical and chemical indicators has been developed, with the aim to apply it to the retrieval of tropospheric BrO columns from space nadir measurements. The adopted parameterization is based on three years of output data from the 3-D chemistry transport model BASCOE. The impact of the atmospheric dynamics on the stratospheric BrO distribution is treated by means of Br<sub>y</sub>/ozone correlations built from 3-D-CTM model results, while photochemical effects are taken into account using stratospheric NO<sub>2</sub> columns as an indicator of the BrO/Br<sub>y</sub> ratio. The model simulations have been optimized for bromine chemistry and budget, and validated through comparisons using an extensive data set of ground-based, balloon-borne and satellite limb (SCIAMACHY) stratospheric BrO observations.