Acta Crystallographica Section E (Mar 2012)

N2-(7-Bromo-9-butyl-9H-carbazol-2-yl)-9,9-diethyl-N2,N7,N7-triphenyl-9H-fluorene-2,7-diamine

  • Edward R. T. Tiekink,
  • K. R. Justin Thomas,
  • Seik Weng Ng,
  • Abhishek Baheti

DOI
https://doi.org/10.1107/S160053681200791X
Journal volume & issue
Vol. 68, no. 3
pp. o860 – o861

Abstract

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In the title molecule, C51H46BrN3, the central fluorene residue is planar (r.m.s. deviation = 0.0203 Å), as is the carbazole system (r.m.s. deviation = 0.0154 Å), and these groups are almost orthogonal [dihedral angle = 79.72 (3)°]. The three-dimensional architecture is consolidated by C—H...π interactions. The butyl substituent is disordered with two sites resolved for the terminal propyl atoms; the major component had a site-occupancy factor of 0.686 (3).