Nature Communications (Oct 2022)
Constitutional isomerism of the linkages in donor–acceptor covalent organic frameworks and its impact on photocatalysis
- Jin Yang,
- Samrat Ghosh,
- Jérôme Roeser,
- Amitava Acharjya,
- Christopher Penschke,
- Yusuke Tsutsui,
- Jabor Rabeah,
- Tianyi Wang,
- Simon Yves Djoko Tameu,
- Meng-Yang Ye,
- Julia Grüneberg,
- Shuang Li,
- Changxia Li,
- Reinhard Schomäcker,
- Roel Van De Krol,
- Shu Seki,
- Peter Saalfrank,
- Arne Thomas
Affiliations
- Jin Yang
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Samrat Ghosh
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Jérôme Roeser
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Amitava Acharjya
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Christopher Penschke
- Institute of Chemistry/Theoretical Chemistry, University of Potsdam
- Yusuke Tsutsui
- Department of Molecular Engineering, Kyoto University
- Jabor Rabeah
- Leibniz-Instituts für Katalyse e.V. an der Universität Rostock
- Tianyi Wang
- Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH
- Simon Yves Djoko Tameu
- Department of Chemistry/Chemical Reaction Engineering, Technische Universität Berlin
- Meng-Yang Ye
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Julia Grüneberg
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Shuang Li
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Changxia Li
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- Reinhard Schomäcker
- Department of Chemistry/Chemical Reaction Engineering, Technische Universität Berlin
- Roel Van De Krol
- Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH
- Shu Seki
- Department of Molecular Engineering, Kyoto University
- Peter Saalfrank
- Institute of Chemistry/Theoretical Chemistry, University of Potsdam
- Arne Thomas
- Department of Chemistry/Functional Materials, Technische Universität Berlin
- DOI
- https://doi.org/10.1038/s41467-022-33875-9
- Journal volume & issue
-
Vol. 13,
no. 1
pp. 1 – 10
Abstract
Systematic investigation of isomerism in covalent organic frameworks (COFs) can provide key insights into their properties. Here, the authors reveal that the constitutional isomerism of the linkage i.e., linkage orientations distinctly impact COFs’ structural and photophysical properties.
