Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water

Atsushi Ohtaka; Toshiyuki Okagaki; Go Hamasaka; Yasuhiro Uozumi; Tsutomu Shinagawa; Osamu Shimomura; Ryôki Nomura

doi:10.3390/catal5010106

Catalysts (Feb 2015)

Application of “Boomerang” Linear Polystyrene-Stabilized Pd Nanoparticles to a Series of C-C Coupling Reactions in Water

Atsushi Ohtaka,
Toshiyuki Okagaki,
Go Hamasaka,
Yasuhiro Uozumi,
Tsutomu Shinagawa,
Osamu Shimomura,
Ryôki Nomura

Affiliations

Atsushi Ohtaka: Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
Toshiyuki Okagaki: Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
Go Hamasaka: Institute for Molecular Science (IMS), Higashiyama 5-1, Myodaiji, Okazaki 444-8787, Japan
Yasuhiro Uozumi: Institute for Molecular Science (IMS), Higashiyama 5-1, Myodaiji, Okazaki 444-8787, Japan
Tsutomu Shinagawa: Osaka Municipal Technical Research Institute, 1-6-50 Morinomiya, Joto, Osaka, 536-8553, Japan
Osamu Shimomura: Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan
Ryôki Nomura: Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka 535-8585, Japan

DOI: https://doi.org/10.3390/catal5010106
Journal volume & issue: Vol. 5, no. 1
pp. 106 – 118

Abstract

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The application of a catch-and-release system for soluble Pd species between water (reaction medium) and polystyrene (polymer support) was examined in the Suzuki coupling reaction with 2-bromothiophene and the Heck reaction with styrene or bromobenzene. Although a slight increase in particle size was observed by TEM after re-stabilization of the Pd species on linear polystyrene, no agglomeration was observed.

Published in Catalysts

ISSN: 2073-4344 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Technology: Chemical technology; Science: Chemistry
Website: https://www.mdpi.com/journal/catalysts

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