Molecules (Mar 2021)

Structural, Optical and Electrical Properties of Cu<sub>0.6</sub>Co<sub>x</sub>Zn<sub>0.4−x</sub>Fe<sub>2</sub>O<sub>4</sub> (x = 0.0, 0.1, 0.2, 0.3, 0.4) Soft Ferrites

  • W. Aslam Farooq,
  • Muhammad Sajjad Ul Hasan,
  • Muhammad Iftikhar Khan,
  • Ahmad Raza Ashraf,
  • Muhammad Abdul Qayyum,
  • Nafeesah Yaqub,
  • Mona A. Almutairi,
  • Muhammad Atif,
  • Atif Hanif

DOI
https://doi.org/10.3390/molecules26051399
Journal volume & issue
Vol. 26, no. 5
p. 1399

Abstract

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A series of cobalt-inserted copper zinc ferrites, Cu0.6CoxZn0.4−xFe2O4 (x = 0.0, 0.1, 0.2, 0.3, 0.4) having cubic spinel structure were prepared by the coprecipitation method. Various characterization techniques, including XRD, FTIR, UV-vis and I–V were used to investigate structural optical and electrical properties, respectively. The lattice constant was observed to be decreased as smaller ionic radii Co2+ (0.74 Å) replaced the higher ionic radii Zn2+ (0.82 Å). The presence of tetrahedral and octahedral bands was confirmed by FTIR spectra. Optical bandgap energy was determined in the range of 4.44–2.05 eV for x = 0.0 to 0.4 nanoferrites, respectively. DC electrical resistivity was measured and showed an increasing trend (5.42 × 108 to 6.48 × 108 Ω·cm) with the addition of cobalt contents as cobalt is more conductive than zinc. The range of DC electrical resistivity (108 ohm-cm) makes these nanomaterials potential candidates for telecommunication devices.

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