Nanomaterials (Apr 2015)

Dealloying of Cu-Based Metallic Glasses in Acidic Solutions: Products and Energy Storage Applications

  • Zhifeng Wang,
  • Jiangyun Liu,
  • Chunling Qin,
  • Hui Yu,
  • Xingchuan Xia,
  • Chaoyang Wang,
  • Yanshan Zhang,
  • Qingfeng Hu,
  • Weimin Zhao

DOI
https://doi.org/10.3390/nano5020697
Journal volume & issue
Vol. 5, no. 2
pp. 697 – 721

Abstract

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Dealloying, a famous ancient etching technique, was used to produce nanoporous metals decades ago. With the development of dealloying techniques and theories, various interesting dealloying products including nanoporous metals/alloys, metal oxides and composites, which exhibit excellent catalytic, optical and sensing performance, have been developed in recent years. As a result, the research on dealloying products is of great importance for developing new materials with superior physical and chemical properties. In this paper, typical dealloying products from Cu-based metallic glasses after dealloying in hydrofluoric acid and hydrochloric acid solutions are summarized. Several potential application fields of these dealloying products are discussed. A promising application of nanoporous Cu (NPC) and NPC-contained composites related to the energy storage field is introduced. It is expected that more promising dealloying products could be developed for practical energy storage applications.

Keywords