Hydrogel Leclanché Cell: Construction and Characterization

Abstract

A liquid-to-gel based Leclanché cell has been designed, constructed and characterized for use in implantable medical devices and other applications where battery access is limited. This well-established chemistry will provide reliable electrochemical potential over a wide range of applications and the novel construction provides a solution for the re-charging of electrodes in hard to access areas such as an internal pacemaker. The traditional Leclanché cell, comprised of zinc (anode) and manganese dioxide (cathode), conductive carbon powder (acetylene black or graphite), and aqueous electrolyte (NH4Cl and ZnCl2), has been suspended in an agar hydrogel to simplify construction while maintaining electrochemical performance. Agar hydrogel, saturated with electrolyte, serves as the cell support and separator allowing for the discharged battery suspension to be easily replaced once exhausted. Different amounts of active anode/cathode material have been tested and discharge characteristics have been plotted. It has been found that for the same amount of active material, acetylene black batteries have higher energy density compared to graphite batteries. Graphite batteries also discharge faster compared to acetylene black batteries. The results support further development of liquid batteries that can be replaced and refilled upon depletion.

Keywords

• hydrogel
• leclanché
• refillable
• primary cell
• liquid battery
• liquid cathode
• liquid anode
• graphite
• acetylene black
• energy density