Journal of Saudi Chemical Society (Nov 2017)

A recyclable Fe3O4-supported cobalt nanocatalyst for the epoxidation of olefins using aqueous hydrogen

  • Jiangfeng Huang,
  • Yingting Wang,
  • Zheng Hao,
  • Xinhua Peng

DOI
https://doi.org/10.1016/j.jscs.2015.12.005
Journal volume & issue
Vol. 21, no. 7
pp. 811 – 816

Abstract

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A novel and green method of olefin epoxidation was developed by using aqueous hydrogen peroxide as the terminal oxidation agent over Co-Fe3O4 magnetic nanoparticles catalyst in acetonitrile medium. This process showed excellent conversion and selectivity toward both terminal and substituted olefins. Co-Fe3O4 magnetic nanoparticles could be recycled and reused without significant loss of catalytic activity in this transformation.

Keywords