Study of Crystal Characterization and Chemical Interaction in the Ternary System Ho-Sb-Te

Abstract

Complex methods of physical and chemical analysis: differential thermal analysis (DTA), X-ray phase analysis (XRD), microstructural analysis (MSA), as well as density and microhardness measurements, were used to study the nature of chemical interaction in the Ho-Sb-Te ternary system over the entire concentration range along the following sections:1. Sb2Te3-Ho2Te3, 2. Sb2Te3-HoTe, 3. HoTe-Sb, 4. HoSb-HoTe, 5. Sb2Te3-Ho, 6. HoSb-Te. The projection of the liquidus surface of the ternary system and the diagrams of the state of internal sections were constructed according to experimental data and literature data on binary systems: Sb-Te, Sb-Ho, Ho-Te. It is established that sections (1), (2), (3), (4) are quasi-binary, and (5), (6) are non-quasi-binary sections of the ternary system. The incongruently melting compound HoSbTe3 is formed in the Sb2Te3-Ho2Te3 system and the area of solid solutions based on Sb2Te3 ~ 3‑5 mol% at 300K was found.

Keywords

• system
• cut
• liquidus
• quasi binary
• non-quasi binary