Trimethyl 4,4′,4′′-(ethene-1,1,2-triyl)tribenzoate

Melvin J. G. Lesley; Koray Ozhan; Herman H.-Y. Sung; Ian D. Williams

doi:10.1107/S2414314620004174

IUCrData (Mar 2020)

Trimethyl 4,4′,4′′-(ethene-1,1,2-triyl)tribenzoate

Melvin J. G. Lesley,
Koray Ozhan,
Herman H.-Y. Sung,
Ian D. Williams

Affiliations

Melvin J. G. Lesley: Department of Chemistry, Southern Connecticut State University, 501 Crescent, Street, New Haven, CT, 06515-1355, USA
Koray Ozhan: Department of Chemistry, Southern Connecticut State University, 501 Crescent, Street, New Haven, CT, 06515-1355, USA
Herman H.-Y. Sung: Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong
Ian D. Williams: Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong

DOI: https://doi.org/10.1107/S2414314620004174
Journal volume & issue: Vol. 5, no. 3
p. x200417

Abstract

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The title compound, C26H22O6, is formed as the major product from the reaction between syn-1,2-bis(pinacolatoboron)-1,2-bis(4-methylcarboxyphenyl)ethene and excess methyl 4-iodobenzoate in basic DMSO using a palladium catalyst at 80°C via Suzuki coupling followed by protodeboronation. Crystals were grown by slow evaporation of a hexanes solution at room temperature.

Published in IUCrData

ISSN: 2414-3146 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://iucrdata.iucr.org

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