Polímeros (Jan 2013)

Optically transparent membrane based on bacterial cellulose/polycaprolactone

  • H. S. Barud,
  • S. J. L. Ribeiro,
  • C. L. P Carone,
  • R. Ligabue,
  • Sandra Einloft,
  • P. V. S. Queiroz,
  • A. P. B. Borges,
  • V. D. Jahno

Journal volume & issue
Vol. 23, no. 1
pp. 135 – 142

Abstract

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Optically transparent membranes from bacterial cellulose (BC)/polycaprolactone (PCL) have been prepared by impregnation of PCL acetone solution into dried BC membranes. UV-Vis measurements showed an increase on transparency in BC/PCL membrane when compared with pristine BC. The good transparency of the BC/PCL can be related to the presence of BC nanofibers associated with deposit of PCL nano-sized spherulites which are smaller than the wavelength of visible light and practically free of light scattering. XRD results show that cellulose type I structure is preserved inside the BC/PCL membrane, while the mechanical properties suggested indicated that PCL acts as a plasticizer for the BC membrane. The novel BC/PCL membrane could be used for preparation of fully biocompatible flexible display and biodegradable food packaging.

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