Журнал Белорусского государственного университета: Химия (Apr 2022)

Synthesis and structure of сopper(II) thiocyanate and nitrate complexes with 1-tert-butyl1H-1,2,4-triazolе

  • Mikhail M. Degtyarik,
  • Alexander S. Lyakhov,
  • Inna M. Grigorieva,
  • Ludmila S. Ivashkevich,
  • Yuri V. Grigoriev,
  • Oleg A. Ivashkevich

DOI
https://doi.org/10.33581/2520-257X-2022-1-83-95
Journal volume & issue
no. 1
pp. 83 – 95

Abstract

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Complexes [Сu(NCS)2L3], [Сu(NO3)2L4] and [Cu(NCS)2L4]·L have been prepared by direct synthesis involving the interaction of metallic copper, ammonium salts NH4X (Х = NCS, NO3) and 1-tert-butyl-1H-1,2,4-triazole (L). Their composition and structure were determined by elemental analysis, single crystal X-ray analysis, and IR spectroscopy (range of 4000–500 cm–1). All the complexes showed mononuclear structure. In them triazole acts as a monodentate ligand, being coordinated by the N4 atom of the heterocycle. The NCS– and NO–3 anions display monodentate N- and O-coordination, accordingly. In [Сu(NCS)2L3], copper(II) cation has square-pyramidal environment of nitrogen atoms of two ligands L and two thiocyanate anions in the basal sites, and one nitrogen atom of ligand L in the apical position. In complexes [Сu(NO3)2L4] and [Cu(NCS)2L4]·L, copper(II) cations are octahedrally surrounded by nitrogen atoms of ligand L in the equatorial sites and by O or N atoms of corresponding anions in the axial positions.

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