[6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate

Panagiotis Kouvatsis; Dimitrios Glykos; John C. Plakatouras; Gerasimos Malandrinos

doi:10.3390/M1724

Molbank (Sep 2023)

[6-(Furan-2-yl)-2,2′-bipyridine]bis(triphenylphosphine) Copper(I) Tetrafluoroborate

Panagiotis Kouvatsis,
Dimitrios Glykos,
John C. Plakatouras,
Gerasimos Malandrinos

Affiliations

Panagiotis Kouvatsis: Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece
Dimitrios Glykos: Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece
John C. Plakatouras: Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece
Gerasimos Malandrinos: Laboratory of Inorganic Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece

DOI: https://doi.org/10.3390/M1724
Journal volume & issue: Vol. 2023, no. 3
p. M1724

Abstract

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A new heteroleptic Cu(I) complex, [Cu(L)(PPh3)2][BF4] (L = 6-(furan-2-yl)-2,2′-bipyridine; PPh3 = triphenylphosphine), was successfully synthesized and characterized. Its molecular structure was determined using X-ray crystallography, and NMR as well as HR-ESI-MS data confirm the compound’s integrity in solution. The complex exhibits emission solely in the solid state (λem = 576 nm) and demonstrates a photoluminescence quantum yield of 2.5%.

Published in Molbank

ISSN: 1422-8599 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Science: Chemistry: Inorganic chemistry
Website: https://www.mdpi.com/journal/molbank

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