Reversible addition fragmentation chain transfer polymerization - RAFT

Abstract

The fundamentals of controlled radical polymerization are presented in this review. The paper focuses on reversible addition fragmentation chain transfer (RAFT) polymerization. The mechanism and specifics of this type of polymerization are discussed, as are the possibilities of synthesizing complex macro-molecular structures. The synthesis and properties of RAFT agents, of the general structure Z-C(=S)-S-R, are presented.

Keywords

• controlled radical polymerization
• reversible addition fragmentation chain transfer
• thio compounds