Química Nova (Jan 2008)

Calor e trabalho: são estes conceitos invariantes sob a permuta sistema-vizinhança? Heat and work concepts: are they invariant under a system-surroundings interchange?

  • Joaquim Anacleto,
  • José M. Ferreira

DOI
https://doi.org/10.1590/S0100-40422008000700048
Journal volume & issue
Vol. 31, no. 7
pp. 1881 – 1884

Abstract

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It is argued that the invariants associated to the First Law of Thermodynamics and to the concept of identical processes lead to a clear definition of heat and work. The conditions for heat and work to be invariant under a system-surroundings interchange are also investigated. Finally, examples are presented to illustrate the above conditions.

Keywords