Treatment of Liquid Fraction of Digestate by Integrated Process Struvite Precipitation—Forward Osmosis

Abstract

The research undertaken in this paper was aimed at determining the effect of struvite precipitation, one of the potential products that can be obtained during digestate management, on the performance of the non-pressurized membrane process—forward osmosis (FO). The effect of using an integrated struvite precipitation—forward osmosis process to treat the digestate liquid on the changes in the properties of organic substances present in the treated solution (particle size distribution, ζ-potential) was analysed as well. The study was conducted for the liquid fraction of municipal waste biogas plant digestate. The obtained results demonstrate the suitability of this process for recovering water from liquid digestate. It was found that forward osmosis conducted for a digestate pre-treated by chemical struvite precipitation leads to higher water flux values and increased salt concentration in the receiving solution (from 0.5 to 3 mol/dm3 NaCl). There is practically no concomitant infiltration of organic substances into the receiving solution. Therefore, the use of 3 mol/dm3 NaCl as a draw solution results in the recovery of the highest volume of water per unit of time. An analysis of the particle size distribution shows that the removal of the macromolecular fraction of organic compounds from the digestate mainly takes place simultaneously with the chemical precipitation of struvite. It was found that an increase in the concentration of the draw solution, which allows for greater water recovery, resulted in the aggregation of the concentrated organic molecules.

Keywords

• digestate
• municipal waste biogas plant
• struvite precipitation
• forward osmosis
• size distribution
• zeta potential