Study on the alcoholysis of dichloromethylvinylsilane(甲基乙烯基二氯硅烷乙醇解反应的研究)

Affiliations

XUWen-yuan(徐文媛): 1.Department of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系，江西　南昌　330013)
ZHONGYun(钟昀): 1.Department of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系，江西　南昌　330013)
LIUXian-liang(刘显亮): 2.Editorial Board of Journal, Jiangxi Normal University, Nanchang 330027, China( 2.江西师范大学学报编辑部，江西　南昌　330027)
HEZhong-yi(何忠义): 1.Department of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系，江西　南昌　330013)
ZHENGLong-zhen(郑龙珍): 1.Department of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China( 1.华东交通大学化学化工系，江西　南昌　330013)

Abstract

对甲基乙烯基二氯硅烷的乙醇解反应进行了理论（采用B3LYP/6-31G(D)方法）和实验（溶剂法）研究，发现反应较容易进行.主产物为甲基乙烯基二乙氧基硅烷；反应宜按乙醇滴加入氯硅烷的方式进行.理论和实验结果比较吻合.计算溶剂效应，表明溶剂的存在有利于排除副产物HCI的干扰，阻碍副反应的进行.

ISSN: 1008-9497 (Print)
Publisher: Zhejiang University Press
Country of publisher: China
LCC subjects: Science: Mathematics: Instruments and machines: Electronic computers. Computer science; Science: Physics
Website: https://www.zjujournals.com/sci/EN/1008-9497/home.shtml