Photocatalytic cyclization of nitrogen-centered radicals with carbon nitride through promoting substrate/catalyst interaction

Mingcheng Yang; Ronghong Lian; Xirui Zhang; Chong Wang; Jiajia Cheng; Xinchen Wang

doi:10.1038/s41467-022-32623-3

Nature Communications (Aug 2022)

Photocatalytic cyclization of nitrogen-centered radicals with carbon nitride through promoting substrate/catalyst interaction

Mingcheng Yang,
Ronghong Lian,
Xirui Zhang,
Chong Wang,
Jiajia Cheng,
Xinchen Wang

Affiliations

Mingcheng Yang: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University
Ronghong Lian: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University
Xirui Zhang: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University
Chong Wang: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University
Jiajia Cheng: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University
Xinchen Wang: State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University

DOI: https://doi.org/10.1038/s41467-022-32623-3
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 9

Abstract

Read online

Carbon nitride catalysts with positively charged surfaces and abundant −NH2 are found to be effective photocatalysts for dihydropyrazole synthesis. A surface-mediated mechanism where deprotonated intermediates interact with the surface is proposed.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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