Acta Crystallographica Section E (Jul 2011)

1-[2,2-Bis(1,3-benzimidazol-1-ylmethyl)-3-bromopropyl]-1,3-benzimidazole

  • Tai-Bao Wei,
  • Yan-Yun Lu,
  • Cheng Cao,
  • Hong Yao,
  • You-Ming Zhang

DOI
https://doi.org/10.1107/S1600536811023464
Journal volume & issue
Vol. 67, no. 7
pp. o1833 – o1833

Abstract

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The title compound, C26H23BrN6, has been synthesized as a potential ligand for the construction of metal–organic frameworks. The three benzimidazolyl groups present three potential coordination nodes. The dihedral angles between the benzimidazole ring systems are 74.03 (10), 66.49 (9) and 74.09 (9)°. The structure contains large voids, which contain highly disordered solvent molecules that may be CH3CH2OH. Since the solvent molecules could not be located, the PLATON/SQUEEZE procedure [Spek (2009). Acta Cryst. D65, 148–155] was used.