An overview on the effect of dissolved water on the viscosity of soda lime silicate melts

Abstract

In this review article, the impact of dissolved water on the viscous properties of soda lime silicate melts is addressed against the background of the upcoming switch from natural gas to hydrogen combustion. This change will lead to an increase in the total water content of the glasses by up to 0.4 mol%. In order to better define possible influences of water speciation, water-rich glasses were synthesised under increasing pressure up to the kbar range. It is shown that a distinction must be made between the influence of dissolved OH-groups and H2O-molecules in order to accurately reflect the dependence of isokom temperatures on water content. In addition, an increase of one order of magnitude in the tolerance to higher deformation rates was observed for the range of expected increased water contents during isothermal deformation processes, which is based on the time-temperature superposition principle, i.e. congruent flow curves were determined under isokomal conditions.

Keywords

• Water in glass
• Viscosity
• Soda lime silicate glasses
• Shear thinning
• Hydrogen melting