Dominant Contributions of Secondary Aerosols and Vehicle Emissions to Water-Soluble Inorganic Ions of PM<sub>2.5</sub> in an Urban Site in the Metropolitan Hangzhou, China
Chun Xiong,
Shaocai Yu,
Xue Chen,
Zhen Li,
Yibo Zhang,
Mengying Li,
Weiping Liu,
Pengfei Li,
John H. Seinfeld
Affiliations
Chun Xiong
Research Center for Air Pollution and Health, Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China
Shaocai Yu
Research Center for Air Pollution and Health, Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China
Xue Chen
Research Center for Air Pollution and Health, Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China
Zhen Li
Research Center for Air Pollution and Health, Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China
Yibo Zhang
Research Center for Air Pollution and Health, Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China
Mengying Li
Research Center for Air Pollution and Health, Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China
Weiping Liu
Research Center for Air Pollution and Health, Key Laboratory of Environmental Remediation and Ecological Health, Ministry of Education, College of Environmental and Resource Sciences, Zhejiang University, Hangzhou 310058, China
Pengfei Li
College of Science and Technology, Hebei Agricultural University, Baoding 071000, China
John H. Seinfeld
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA
Water soluble inorganic ions (WSIIs) are important components in PM2.5 and could strongly affect the acidity and hygroscopicity of PM2.5. In order to achieve the seasonal characteristics and determine the potential sources of WSIIs in PM2.5 in Hangzhou, online systems were used to measure hourly mass concentrations of WSIIs (SO42−, NO3−, NH4+, Cl−, Na+, K+, Ca2+ and Mg2+) as well as PM2.5, NO2 and SO2 at an urban site for one month each season (May, August, October, December) in 2017. Results showed that the hourly mass concentrations of PM2.5 during the whole campaign varied from 1 to 292 μg·m−3 with the mean of 56.03 μg·m−3. The mean mass concentration of WSIIs was 26.49 ± 20.78 μg·m−3, which contributed 48.28% to averaged PM2.5 mass. SNA (SO42−, NO3− and NH4+) were the most abundant ions in PM2.5 and on average, they comprised 41.57% of PM2.5 mass. PM2.5, NO2, SO2 and WSIIs showed higher mass concentrations in December, possibly due to higher energy consumption emissions, unfavorable meteorological factors (e.g., lower wind speed and temperature) and regional transport. Results from PCA models showed that secondary aerosols and vehicle emissions were the dominant sources of WSIIs in the observations. Our findings highlight the importance of stronger controls on precursor (e.g., SO2 and NO2) emissions in Hangzhou, and show that industrial areas should be controlled at local and regional scales in the future.
