An Alternative Use of Olive Pomace as a Wide-Ranging Bioremediation Strategy to Adsorb and Recover Disperse Orange and Disperse Red Industrial Dyes from Wastewater
Vito Rizzi,
Francesco D’Agostino,
Jennifer Gubitosa,
Paola Fini,
Andrea Petrella,
Angela Agostiano,
Paola Semeraro,
Pinalysa Cosma
Affiliations
Vito Rizzi
Università degli Studi “Aldo Moro” di Bari, Dip. Chimica, Via Orabona, 4, 70126 Bari, Italy
Francesco D’Agostino
Università degli Studi “Aldo Moro” di Bari, Dip. Chimica, Via Orabona, 4, 70126 Bari, Italy
Jennifer Gubitosa
Università degli Studi “Aldo Moro” di Bari, Dip. di Farmacia-Scienze del Farmaco, Via Orabona 4, 70126 Bari, Italy
Paola Fini
Consiglio Nazionale delle Ricerche CNR-IPCF, UOS Bari, Via Orabona, 4, 70126 Bari, Italy
Andrea Petrella
Dipartimento di Ingegneria Civile, Ambientale, Edile, del Territorio e di Chimica, Politecnico di Bari, Orabona, 4, 70125 Bari, Italy
Angela Agostiano
Università degli Studi “Aldo Moro” di Bari, Dip. Chimica, Via Orabona, 4, 70126 Bari, Italy
Paola Semeraro
Università degli Studi “Aldo Moro” di Bari, Dip. Chimica, Via Orabona, 4, 70126 Bari, Italy
Pinalysa Cosma
Università degli Studi “Aldo Moro” di Bari, Dip. Chimica, Via Orabona, 4, 70126 Bari, Italy
In this paper, industrial dyes, Disperse Red and Disperse Orange, were studied as model pollutants to show the excellent performance of olive pomace (OP) in sequestering and recovering these dangerous dyes from wastewater. The nature of interactions involved between dyes and OP were inferred by changing several parameters: contact time, pomace dosage, pH and temperature values. Visible spectroscopy was mainly used to obtain the percentage of the removed dyes, while SEM (scanning electron microscopy), FTIR-ATR (Fourier transform infra-red spectroscopy in total attenuated reflectance), TG (thermo gravimetric) and XPS (X-ray photoelectron spectroscopy) analyses were used to carefully investigate the systems. The recovery of dyes was also obtained using glacial acetic acid, the auxiliary solvent used during the dyeing processes, enabling the recycling of both of the adsorbent material and dyes presenting a green and a wide-ranging strategic approach.