Doubly linked chiral phenanthrene oligomers for homogeneously π-extended helicenes with large effective conjugation length

Abstract

Helically twisted conductive nanocarbon materials are applicable to optoelectronic and electromagnetic molecular devices but the design of nanocarbons with an absorption edge in the low energy region is challenging. Here, the authors report the synthesis of a helically fused oligophenanthrenes and demonstrate an increased effective conjugation length leading to an absorption edge in the NIR region.