Nature Communications (May 2016)

Visualizing non-equilibrium lithiation of spinel oxide via in situ transmission electron microscopy

  • Kai He,
  • Sen Zhang,
  • Jing Li,
  • Xiqian Yu,
  • Qingping Meng,
  • Yizhou Zhu,
  • Enyuan Hu,
  • Ke Sun,
  • Hongseok Yun,
  • Xiao-Qing Yang,
  • Yimei Zhu,
  • Hong Gan,
  • Yifei Mo,
  • Eric A. Stach,
  • Christopher B. Murray,
  • Dong Su

DOI
https://doi.org/10.1038/ncomms11441
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 9

Abstract

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Non-equilibrium intercalation reactions may determine the performance of lithium-ion battery materials undergoing lithiation, but it is difficult to probe in real time. Here, the authors use in situelectron microscopy to identify kinetically-driven phase evolution in magnetite single nanoparticles.