Schiff Base Ligand 3-(-(2-Hydroxyphenylimino) Methyl)-4H-Chromen-4-One as Colorimetric Sensor for Detection of Cu2+, Fe3+, and V5+ in Aqueous Solutions

Abstract

The ligand 3-(-(2-hydroxyphenylimino) methyl)-4H-chromen-4-one (SL) has been synthesized and examined as a chemosensor for some metal ions in aqueous solutions based on colorimetric analysis. Color changes were monitored using UV–visible spectroscopy. Binding stoichiometry and limit of detection (LOD) were estimated using titration experimentation based on UV–visible absorbance and Job’s plot. The synthesized ligand was tested for selectivity in the presence of several cations and was examined for possible utility as a chemosensor in real water samples. The results indicated sensing ability and selectivity for Cu2+, Fe3+, and V5+. Stable complexes were formed between SL and Cu2+, Fe3+, and V5+, and the ligand-to-metal binding stoichiometry was found 2 : 1 in the SL-Cu2+ and SL-Fe3+ complexes, and 1 : 1 in the SL-V5+ complex. The results of LOD and bending constant were (7.03 μM, 1.37 × 104 M−1), (5.16 μM, 2.01 × 104 M−1), and (5.94 μM, 1.82 × 104 M−1) for Cu2+, Fe3+, and V5+, respectively.