IUCrData (May 2016)

Ethyl 2-(3,5-difluorophenyl)quinoline-4-carboxylate: a second triclinic polymorph

  • S. Shashidhar Bharadwaj,
  • Karthik Kumara,
  • Boja Poojary,
  • H. S. Yathirajan,
  • K. Byrappa,
  • N. K. Lokanath,
  • S. Madan Kumar

DOI
https://doi.org/10.1107/S2414314616007392
Journal volume & issue
Vol. 1, no. 5
p. x160739

Abstract

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The title compound, C18H13F2NO2, is a polymorph of the structure reported by Sunitha et al. [Acta Cryst. (2015), E71, o341–o342]. Both compounds crystallize in the triclinic space group P\overline{1}. The principal difference between the two polymorphs lies in the orientation of the carboxylate substituents with respect to the planes of the quinoline ring systems. In the crystal, the packing features C—H...O hydrogen bonds together with short C—F...π and π–π interactions [inter-centroid distances of 3.8199 (11), 3.6825 (12) and 3.8722 (13) Å].

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