2,3-Dihydro-1λ6,2-benzothiazine-1,1,4-trione

Abstract

In the title compound, C8H7NO3S, the benzene ring is oriented at a dihedral angle of 69.25 (7)° to the S and O atoms of the sulfonyl group. The heterocyclic ring approximates to an envelope, with the N atom in the flap position. In the crystal, molecules are linked by N—H...Oc (c = carbonyl) hydrogen bonds, forming C(5) chains along [001]. Two R22(10) loops arise from pairs of C—H...O hydrogen bonds and a weak aromatic π–π stacking interaction [centroid–centorid separation = 3.8404 (11) Å] also occurs.