Crystal structure of (μ-N,N′-dibenzyldithiooxamidato-κN,S:N′,S′)bis[(η3-crotyl)palladium(II)]

Acta Crystallographica Section E: Crystallographic Communications. 2015;71(2):m40-m41 DOI 10.1107/S2056989015001292

 

Journal Homepage

Journal Title: Acta Crystallographica Section E: Crystallographic Communications

ISSN: 2056-9890 (Online)

Publisher: International Union of Crystallography

LCC Subject Category: Science: Chemistry

Country of publisher: United Kingdom

Language of fulltext: English

Full-text formats available: PDF, HTML

 

AUTHORS


Giuseppe Bruno (Department of Chemical Sciences, University of Messina, Via F. Stagno d'Alcontres 31, 98166 Messina, Italy)

Santo Lanza (Department of Chemical Sciences, University of Messina, Via F. Stagno d'Alcontres 31, 98166 Messina, Italy)

Antonino Giannetto (Department of Chemical Sciences, University of Messina, Via F. Stagno d'Alcontres 31, 98166 Messina, Italy)

Alessandro Sacca (Department of Chemical Sciences, University of Messina, Via F. Stagno d'Alcontres 31, 98166 Messina, Italy)

Hadi Amiri Rudbari (Faculty of Chemistry, University of Isfahan, Isfahan, Iran)

EDITORIAL INFORMATION

Blind peer review

Editorial Board

Instructions for authors

Time From Submission to Publication: 3 weeks

 

Abstract | Full Text

In the centrosymmetric dinuclear title compound, [Pd2(C4H7)2(C16H14N2S2)], the metal atom is η3-coordinated by three C atoms of a crotyl ligand [Pd—C = 2.147 (4), 2.079 (5) and 2.098 (5) Å], the longest distance influenced by the steric interaction with the benzyl substituents of the dibenzyldithiooximidate (DTO) ligand. The Pd—N and Pd—S bonds to this ligand are 2.080 (3) and 2.3148 (9) Å, respectively, completing a square-planar coordination environment for PdII. The benzyl groups are oriented so as to maximize the interaction between a benzylic H atom and an S atom, resulting in a dihedral angle of 77.1 (2)° between the benzene rings and the metal complex plane. In the crystal, no inter-complex hydrogen-bonding interactions are present.