Theoretical Prediction for Synthetic Realization: Pyramidal Systems ClE[E′4R4] (E = B–Ga, E′ = C–Ge, R = SiMe3, SiMetBu2): A DFT Study

Olga A. Gapurenko; Vladimir Ya. Lee; Ruslan M. Minyaev; Vladimir I. Minkin

doi:10.1155/2019/3659287

Heteroatom Chemistry (Jan 2019)

Theoretical Prediction for Synthetic Realization: Pyramidal Systems ClE[E′4R4] (E = B–Ga, E′ = C–Ge, R = SiMe3, SiMetBu2): A DFT Study

Olga A. Gapurenko,
Vladimir Ya. Lee,
Ruslan M. Minyaev,
Vladimir I. Minkin

Affiliations

Olga A. Gapurenko: Institute of Physical and Organic Chemistry, Southern Federal University, 344090 Rostov on Don, Russia
Vladimir Ya. Lee: Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305–8571, Ibaraki, Japan
Ruslan M. Minyaev: Institute of Physical and Organic Chemistry, Southern Federal University, 344090 Rostov on Don, Russia
Vladimir I. Minkin: Institute of Physical and Organic Chemistry, Southern Federal University, 344090 Rostov on Don, Russia

DOI: https://doi.org/10.1155/2019/3659287
Journal volume & issue: Vol. 2019

Abstract

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Structure and bonding of hybrid group 13/14 pyramidal molecules ClE[E′4R4] (E = B–Ga, E′ = C–Ge, R = SiMe3, SiMetBu2) were studied by DFT calculations. Six pyramidal structures are suggested for their potential synthetic realization.

Published in Heteroatom Chemistry

ISSN: 1042-7163 (Print); 1098-1071 (Online)
Publisher: Hindawi-Wiley
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Organic chemistry; Science: Chemistry: Inorganic chemistry
Website: https://onlinelibrary.wiley.com/journal/1824

About the journal