Alkaloid Extract of <i>Ageratina adenophora</i> Stem as Green Inhibitor for Mild Steel Corrosion in One Molar Sulfuric Acid Solution

Abstract

Green corrosion inhibitors are of great interest due to their exciting and environmentally friendly behavior in mild steel corrosion control during and after the acid cleaning process. Herein, alkaloids were extracted from the stem of Ageratina adenophora and were ensured by qualitative chemical tests as well as spectroscopic test methods. The corrosion inhibition efficacy of the alkaloids against mild steel corrosion was evaluated by gravimetric, electrochemical and EIS measurement methods. In addition, the adsorption isotherm, free energy of adsorption and thermodynamic parameters of the process were evaluated. The investigations indicated the most promising inhibition efficacy of the alkaloids for mild steel corrosion. The adsorption isotherm study revealed that the adsorption of inhibitor molecules on the MS interface was manifested by dominant physisorption followed by chemisorption. Free energy and thermodynamic parameters are well suited to endothermic processes.

Keywords

• <i>Ageratina adenophora</i>
• alkaloids
• adsorption isotherm
• polarization
• EIS