Polymers (Mar 2022)

Strength, Elastic Properties and Fiber–Matrix Interaction Mechanism in Geopolymer Composites

  • Susana P. Arredondo,
  • Ramón Corral,
  • A. Valenciano,
  • Carlos A. Rosas,
  • Jose M. Gómez,
  • Teresita J. Medina,
  • Magnolia Soto,
  • Jesús M. Bernal

DOI
https://doi.org/10.3390/polym14061248
Journal volume & issue
Vol. 14, no. 6
p. 1248

Abstract

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The current geopolymers have limited mechanical strength against the effect of tension, which makes them susceptible to brittle failure. However, owing to their potential as a sustainable construction material, there is growing interest in improving the poor mechanical properties of geopolymers. This study experimentally investigated crucial properties of polypropylene-fiber-reinforced fly ash-based geopolymer composites. The effects of polypropylene fibers (PPF) addition (0.5%, 1.0% and 1.5% by volume) on the mechanical properties of the geopolymer composites were investigated with respect to compressive and flexural strength, deformation behavior of Young’s and shear moduli, and resilience capacity. In addition, scanning electron microscopy was performed to establish the morphology of the geopolymeric matrix and the fiber–matrix interfacial interaction. The addition of PPF significantly increased the flexural strength: compared with the control, at 7 days it was 27% greater for the 0.5% PPF composite and 65% greater for the 1.0% PPF composite. By 14 days it was 31% and 61% greater, respectively. By contrast, the 1.5% PPF composite had lower strength parameters compared with the control because the fiber dispersion increased the porosity. Similar trends were seen for resilience. The SEM observations showed the dispersion of the fibers and helped elucidate the fiber–matrix interaction mechanism.

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