Design of an efficient magnetic brush solid acid and its catalytic use in organic reactions

Abstract

Abstract In this research, with the Green Chemistry approach, to load more sulfonic acid active sites on catalyst surfaces, a nanocomposite material based on core-shell magnetite coated with vinyl silane and a sulfonated polymeric brush-like structure is designed and synthesized as a new class of efficient solid acid catalysts, referred to as Fe3O4@VS-APS brush solid acid. The synthesized catalyst was comprehensively characterized by a range of instrumental techniques, including XRD, SEM, TEM, FT-IR, EDX, TGA, and VSM. The activity of the catalyst was evaluated in Biginelli, Strecker, and esterification reactions. The Fe3O4@VS-APS brush solid acid has special features, such as easy reusability when a simple magnet is used for four reaction runs, an appropriate balance between hydrophobic and hydrophilic properties on the catalyst surface, and effective catalytic performance in the production of 3,4-dihydropyrimidin-2-one(thione) derivatives, 2-phenyl-2-(phenylamino)acetonitrile and octyl acetate.

Keywords

• Brush solid acid
• Heterogeneous catalyst
• Green chemistry
• Biginelli
• Strecker
• Esterification