Titania supported synergistic palladium single atoms and nanoparticles for room temperature ketone and aldehydes hydrogenation

Long Kuai; Zheng Chen; Shoujie Liu; Erjie Kan; Nan Yu; Yiming Ren; Caihong Fang; Xingyang Li; Yadong Li; Baoyou Geng

doi:10.1038/s41467-019-13941-5

Nature Communications (Jan 2020)

Titania supported synergistic palladium single atoms and nanoparticles for room temperature ketone and aldehydes hydrogenation

Long Kuai,
Zheng Chen,
Shoujie Liu,
Erjie Kan,
Nan Yu,
Yiming Ren,
Caihong Fang,
Xingyang Li,
Yadong Li,
Baoyou Geng

Affiliations

Long Kuai: College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University
Zheng Chen: Department of Chemistry, Tsinghua University
Shoujie Liu: College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University
Erjie Kan: School of Chemical and Biological Engineering, Anhui Polytechnic University
Nan Yu: College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University
Yiming Ren: School of Chemical and Biological Engineering, Anhui Polytechnic University
Caihong Fang: College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University
Xingyang Li: School of Chemical and Biological Engineering, Anhui Polytechnic University
Yadong Li: Department of Chemistry, Tsinghua University
Baoyou Geng: College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-Based Materials, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Normal University

DOI: https://doi.org/10.1038/s41467-019-13941-5
Journal volume & issue: Vol. 11, no. 1
pp. 1 – 9

Abstract

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Highly efficient catalysts are demanded to realize selective hydrogenation of ketone/aldehydes to alcohols under mild conditions. Here, the authors report a TiO2 supported Pd single-atom/nanoparticles synergistic catalyst with outstanding hydrogenation performance at room temperature.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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