Powder production, FAST processing and properties of a Nb-silicide based alloy for high temperature aerospace applications

Abstract

A Nb-silicide based alloy with nominal composition Nb–18Ti–22Si–6Mo-1.5Cr–2Sn-1Hf (at. %), designed for high temperature aerospace applications, was produced via a powder metallurgy (PM) route. The raw elements were arc melted, crushed, and milled to powder, then consolidated using Field Assisted Sintering Technology (FAST). The compressive creep of the alloy was evaluated using electro-thermal mechanical testing (ETMT). The study demonstrated the production of larger 60 mm diameter samples, with potential for further scale up. The microstructure of the FAST alloy, which is comprised of bcc Nbss and tetragonal αNb5Si3 was more homogenous compared with the cast alloy, with some interstitial contamination that occurred during powder production. The FAST alloy had lower density than state of the art Ni-based superalloys and refractory metal complex concentrated alloys (RCCAs) and high entropy alloys (RHEAs), and its yield strength and specific yield strength was higher than those of the latter metallic Ultra high temperature materials (UHTMs) and comparable to those of Nb-silicide based alloys with B addition. The stress exponent n in compressive creep was in the range 1.7–2.6, similar to that of binary Nb–10Si and Nb–16Si alloys and its creep rate at 1200 °C and 100 MPa was similar to that of the MASC alloy (Nb–25Ti–16Si-8Hf-2Al–2Cr (at.%)). Like the latter, the creep of the FAST alloy did not meet the creep goal.

Keywords

• Niobium silicide based alloys
• Refractory metal intermetallic composites
• Field assisted sintering technology
• Spark plasma sintering
• Mechanical properties