Inorganics (Dec 2022)

Ultrathin Films of Silver by Magnetron Sputtering

  • Ana Violeta Filip,
  • Bogdan Alexandru Sava,
  • Rares Victor Medianu,
  • Lucica Boroica,
  • Marius Catalin Dinca,
  • Rovena Pascu,
  • Nicolae Tigau,
  • Andreea Andrei,
  • Antoniu Moldovan,
  • Marius Dumitru,
  • Mihai Oane,
  • Mihai Eftimie

DOI
https://doi.org/10.3390/inorganics10120235
Journal volume & issue
Vol. 10, no. 12
p. 235

Abstract

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The interest in ultrathin silver (Ag) films has increased due to their high surface plasmon resonance for coatings of only a few nm. Low roughness ultrathin films of 1 to 9 nm have been deposited on different substrates, such as polyethylene terephthalate (PET) and optical glass, using radio frequency (RF) magnetron sputtering. Films show good surface plasmon resonance up to 7 nm thickness, as revealed by the ultraviolet-visible (UV-Vis) spectra. The roughness of the films, investigated by Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM), is small, and one can conclude that depositions are smooth and homogeneous. The bandgap values decrease with film thickness. The refractive index of the films, calculated from ellipsometry measurements, leads to values of under 1 visible domain, with minima in the wavelength range of 400–600 nm. The results are useful for obtaining lower roughness ultrathin Ag films with good surface plasmon resonance for photonic applications.

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