Impedance Spectroscopy as a Powerful Tool for Researching Molybdenum-Based Materials with Schiff Base Hydrazones

Abstract

Molybdenum coordination complexes are widely applied due to their biological and pharmacological potential, as well as their performance in different catalytic processes. Parent dioxidomolybdenum Schiff base complexes were prepared via the reaction of [MoO2(acac)2] with a hydrazone Schiff-base tetradentate ligand. A new hydrazone-Schiff base (H2L1 and 2) and its corresponding mononuclear and polynuclear dioxidomolybdenum(VI) complex were synthesized and characterized by spectroscopic methods and elemental analyses, and their thermal behavior was investigated by thermogravimetry. The crystal and molecular structures of H2L2 ligands and the complexes [MoO2(L1)(H2O)], [MoO2(L2)(H2O)], [MoO2(L1)(MeOH)]∙MeOH, [MoO2(L1)(EtOH)]∙EtOH, [MoO2(L1)(2-PrOH)]∙2-PrOH, and [MoO2(L1)]n were determined by single-crystal X-ray diffraction. Using the in situ impedance spectroscopy method (IS), the structural transformations of chosen complexes were followed, and their electrical properties were examined in a wide range of temperatures and frequencies.

Keywords

• molybdenum
• Schiff base
• aroylhydrazone
• impedance spectroscopy
• structural transformations