npj Materials Degradation (Jun 2023)

ISG-2: properties of the second International Simple Glass

  • Joseph V. Ryan,
  • Nicholas J. Smith,
  • James J. Neeway,
  • Joelle T. Reiser,
  • Benjamin Parruzot,
  • Steve Tietje,
  • Elzbieta Bakowska,
  • Jarrod V. Crum,
  • Robert A. Schaut

DOI
https://doi.org/10.1038/s41529-023-00352-7
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 9

Abstract

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Abstract Given the importance of glass materials to society, their durability when exposed to aqueous solutions is a critical area for research, particularly for vitrified radioactive wastes. This spurred an international team to fabricate a standardized composition based on waste immobilization glass called the International Simple Glass (ISG), which has been the subject of numerous experimental and computational studies focused on aqueous corrosion resistance. With the original batch of ISG nearly depleted, the international team designed and fabricated a standard glass material, ISG-2, where half the Ca in the original composition was replaced with Mg by mole. This paper presents information on both the ISG-2 composition and a new batch with the same nominal composition as the original ISG, designated ISG-1, including their homogeneity, their physical and thermal properties. The results of static alteration experiments are presented as well to provide a baseline for future aqueous corrosion performance investigations.