Materials Research Letters (Mar 2024)

800oC-stable D022 superlattice in a NiCrFe-based medium entropy alloy

  • Mei Lin,
  • Jianlin Lu,
  • Yiming Chen,
  • Zhongsheng Yang,
  • Xin Liu,
  • Kaiwei Zhang,
  • Zhijun Wang,
  • Junjie Li,
  • Jincheng Wang,
  • Feng He

DOI
https://doi.org/10.1080/21663831.2024.2309271
Journal volume & issue
Vol. 12, no. 3
pp. 172 – 179

Abstract

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The metastable-stable transition and rapid coarsening of metastable D022 phase remains its Achilles hell, restricting the application of D022-strengthened alloys at service temperatures higher than 650°C. Hence, it is crucial to improve thermal stability of D022 phase. In this work, we report an 800°C-stable D022-Ni3(W0.24Ti0.38Ta0.19Nb0.19) superlattice in the Ni58Cr23Fe10W5Ti2Ta1Nb1 MEA. Experimental results and theoretical analysis showed that the exceptional thermal stability is due to Nb-sublattice occupying elements, low diffusivity of W, and extremely small lattice misfit between the D022 phase and FCC matrix. These findings shed lights on developing high-performance D022-hardened alloys capable of operating at temperatures above 650°C.

Keywords