Non-noble metal based broadband photothermal absorbers for cost effective interfacial solar thermal conversion

Abstract

In recent years, noble metal-based solar absorbers have been extensively studied as their pronounced plasmonic resonances and high solar-to-thermal conversion efficiency. However, the high cost of noble metals is the unavoidable roadblock restricting the way towards scalability. In this work, we report a nickel-based photothermal absorbers, which is capable of realizing an average solar absorption of ∼97% in the range of 400–2500 nm originating from relatively weaker collective plasmonic resonances but more pronounced single electron excitation. Importantly, it is easily fabricated via the straightforward physical deposition and cost-effective with a raw material price of ∼0.3% gold and ∼20% of silver. We used it for interfacial solar vapor generation and realized an evaporation rate of ∼0.9 kg m−2 h−1 under one sun, almost comparable to the counterparts made from noble metals. The excellent performance combined with the cost effective and scalable fabrication process makes it be a promising candidate for mass off-grid solar desalination.

Keywords

• interband transition
• lasmonic absorber
• photothermal conversion
• solar evaporation