Bifunctional catalytic activity of anion-doped LaSrCoO4 for oxygen reduction and evolution reactions

Abstract

Here, we synthesized Co-based, anion-incorporated‍ ‌R‌u‌d‌d‌l‌e‌s­d‌e‌n‌–‌Popper perovskite electrocatalysts (LaSrCoO4−x X y ) and compared their catalytic performances in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). The ORR mechanism with the newly synthesized F-doped LaSrCoO4 catalyst was dominated by a four-electron process, and the number of electrons involved in the reaction increased compared with that for LaSrCoO4. The OER activity of the hydride-doped LaSrCoO4 catalyst was the highest among the LaSrCoO4 system catalysts. Density functional theory calculations revealed that there is a correlation between the Co 3d unoccupied orbital band centre and the OER activity. The addition of anions and substitution of metal sites improved the ORR and OER activities of the catalysts. Our findings confirmed that the addition of heteroatom anions can improve the activity of perovskite-type electrocatalysts, promoting their application in various fields.

Keywords

• perovskite-related compounds
• bifunctional catalyst
• oxygen reduction reaction
• oxygen evolution reaction
• mixed-anion compounds