Optically-transparent opportunistic electromagnetic skins (OTO-EMSs) are proposed to enable outdoor-to-indoor (O2I) millimeter-wave (mmW) wireless communications with existing windows/glass-panels. More in detail, static passive EMSs consisting of optically-transparent conducting patterned layers attached to standard glass-panels are designed. Towards this end, both the phase coverage and the optical transparency of a meshed copper-based meta-atom printed on a non-dedicated insulated glass substrate are optimized. Successively, the feasibility of OTO-EMSs able to support mmW high-efficiency O2I transmissions along non-Snell refraction directions is numerically demonstrated also through full-wave simulations.