Experimental Investigation on Photocatalytic Degradation of Refractory Organics in Biologically Treated Tannery Effluent Using Photocatalysis

Abstract

There is a pressing demand for the introduction of environmentally safe technologies for the industries that supply the basic needs of industrialized societies. Advanced Oxidation Processes may become one of the answers to these uprising pollution management problems in the near future. The present investigation aimed to reduce the refractory organics present in the biologically treated (Activated Sludge Process) tannery effluent using Photocatalysis. The optimum time, pH, dosage of H2O2, and mass of NPAC required for the effective treatment using photocatalysis were found to be 60 mins, 8, 0.2 mg.L-1, and 1g. 100 mL-1, respectively. Although the efficiency of homogeneous photocatalysis was found to be higher than that of heterogeneous photocatalysis, the biodegradability was higher in the latter, with a value of 0.26. The experimental results have proved that photocatalysis could be a promising technology to reduce the refractory organics present in the tannery effluent.

Keywords

• photocatalysis, refractory organics, tannery effluent, advanced oxidation process