Extraction and Characterization of Cellulose from Agricultural By-Products of Chiang Rai Province, Thailand

Abstract

Cellulose is an abundant component of the plant biomass in agricultural waste valorization that may be exploited to mitigate the excessive use of synthetic non-biodegradable materials. This work aimed to investigate the cellulose utilized by alkaline extraction with a prior bleaching process from rice straw, corncob, Phulae pineapple leaves, and Phulae pineapple peels. The bleaching and alkaline extraction process was performed using 1.4% acidified sodium chlorite (NaClO2) and 5% potassium hydroxide (KOH) in all the samples. All the samples, without and with the alkaline process, were characterized for their physico-chemical, microstructure, thermal properties and compared to commercial cellulose (COM-C). The extraction yield was the highest in alkaline-extracted cellulose from the corncob (AE-CCC) sample (p p onset (334.64 °C), and Tmax (364.67 °C) compared to the COM-C and alkaline-treated samples. Therefore, agricultural wastes after harvesting in the Chiang Rai province of Thailand may be subjected to an alkaline process with a prior bleaching process to yield a higher cellulose content that is free of impurities. Thus, the extracted cellulose could be used as an efficient, eco-friendly, and biodegradable material for packaging applications.

Keywords

• agricultural waste valorization
• alkaline extraction
• cellulose
• FTIR
• XRD
• thermal properties