Adsorption of Anionic Dyes from Wastewater onto Magnetic Nanocomposite Powders Synthesized by Combustion Method

Abstract

In the present study, new magnetic nanocomposites were successfully prepared by combustion method, characterized by X-ray diffraction, Fourier transform infrared spectroscopy, magnetic measurements, N2 adsorption–desorption thermal analysis, and scanning electron microscopy, and tested as adsorbents for the removal of anionic dyes (Acid Yellow 42 and Acid Red 213) from aqueous solutions. The influence of process variables solution pH, adsorbent dose, initial dye concentration and temperature on the adsorption was evaluated. The best kinetic model that fitted with experimental data was a pseudo-second order model, and the equilibrium data were correlated by Langmuir isotherm model for the investigated dyes. Maximum removal efficiencies of 98.54% and 97.58% was obtained for Acid Yellow 42 and Acid Red 213, respectively, indicating the superior adsorption capacity of the new synthesized magnetic nanocomposites. The thermodynamic parameters indicated the spontaneous and endothermic nature of the adsorption process.

Keywords

• magnetic nanocomposites
• combustion synthesis
• dye
• adsorption