Electrocatalytic acidic oxygen evolution reaction: From nanocrystals to single atoms
Nadia Ismail,
Fengjuan Qin,
Chaohe Fang,
Dan Liu,
Bihan Liu,
Xiangyu Liu,
Zi‐long Wu,
Zhuo Chen,
Wenxing Chen
Affiliations
Nadia Ismail
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Fengjuan Qin
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Chaohe Fang
CNPC Research Institute of Petroleum Exploration & Development Beijing People's Republic of China
Dan Liu
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Bihan Liu
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Xiangyu Liu
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Zi‐long Wu
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Zhuo Chen
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Wenxing Chen
Energy & Catalysis Center Department of Materials Physics and Chemistry School of Materials Science and Engineering Beijing Institute of Technology Beijing People's Republic of China
Abstract Hydrogen is the most preferred choice as an energy source to replace the nonrenewable energy resources such as fossil fuels due to its beneficial features of abundance, ecofriendly, and outstanding gravimetric energy density. Splitting water through a proton exchange membrane (PEM) electrolyzer is a well‐known method of hydrogen production. But the major impediment is the sluggish kinetics of oxygen evolution reaction (OER). Currently, scientists are struggling to build out an acid‐stable electrocatalyst for OER with low overpotential and excellent stability. In this review, the reaction mechanism and characterization parameters of OER are introduced, and then the improvement method of metal nanocatalysts (noble metal catalysts and noble metal‐free catalysts) in acidic media is discussed. Particularly, the application of single‐atom catalysts in acidic OER is summarized, which is current researching focus. At the same time, we also briefly introduced the cluster phenomenon, which is easy to occur in the preparation of single‐atom catalysts. More importantly, we summarized the in situ characterization methods such as in situ X‐ray absorption spectroscopy, in situ X‐ray photoelectron spectroscopy, and so forth, which are conducive to further understanding of OER reaction intermediates and active sites. Finally, we put forward some opinions on the development of acidic OER.
