A novel atomic mechanism of fcc → hcp → bcc phase transition in a gradient nanostructured compositionally complex alloy

Abstract

This study investigates the plastic deformation-induced fcc → hcp → bcc phase transition within nanograins in an ultra-strong gradient nanostructured surface layer on Fe45Mn35Cr10Co10 compositionally complex alloy (CCA), subjected to a single point cubic boron nitride turning process. High-resolution transmission electron microscope observations reveal a novel atomic movement mechanism of this transition following a unique Nishiyama-Wassermann orientation relationship. Unlike the previously validated Bogers-Burgers-Olson-Cohen model, which follows different orientation relationships and relies on two shear components, this study demonstrates that the phase transition in this CCA is cooperatively completed by two sets of half-partial dislocation dipoles and associated atom shuffling.Statement of NoveltyA novel atomic mechanism of fcc → hcp → bcc phase transition, cooperatively completed by two sets of partial dislocation dipoles and atomic shuffling, provides potential implications for advanced structural materials.

Keywords

• Compositionally complex alloys
• martensitic phase transformation
• high-resolution transmission electron microscopy
• partial dislocation dipole
• atom shuffling