Evaluation of concentration and characterization of potential toxic elements and fluorine in ambient air dust from Iran’s industrial capital: A health risk assessment using Monte Carlo simulation

Abstract

The emission and adsorption of mineral elements to dust from geogenic and anthropogenic sources are health challenges in residential areas. This study investigated, for the first time to the best of our knowledge, the presence of potentially toxic elements (PTEs), rare earth elements (REE) and fluorine (F) in collected dust samples from central Iran. Their associated health risks were estimated based on the Monte Carlo simulation. Results show that the morphology of the collected dust was uniform spherical particles and the predominant elements were Si and Ca. The highest concentration of PTEs was for Ca (mean: 36574 mg/kg) and Fe (mean: 30189 mg/kg) and the mean concentrations of As, Ni, Pb, Mn and Zn exceeded World Health Organization (WHO) guidelines, likely due to the anthropogenic activities such as metal melt factories. Fluorine averaged 159.4 mg/kg, and some detected elements originated from industrial and natural sources. The 5th, 50th, and 95th percentiles of the estimated Hazard Index (HI) were 0.13, 0.43, and 0.77, respectively, in adults and 1.00, 3.03, and 5.99, respectively, in children. The carcinogenic risk (LTCR) for adults and children exceeded the safety range (1 × 10−4), and their highest percentile was calculated at about 2.03 × 10−4 and 1.83 × 10−4, respectively. Furthermore, Ni was the most effective elements in LTCR. As a consequence, findings suggest a high potential carcinogenic risk due to the emission of dust in central Iran, especially for children, and the controlling of possible sources would benefit public health.

Keywords

• Dust
• Potentially toxic elements
• Fluorine
• Rare earth elements
• Human health risk
• Industrial city