Nanomaterials (Jan 2022)

Enhancement of Ferroelectricity in 5 nm Metal-Ferroelectric-Insulator Technologies by Using a Strained TiN Electrode

  • Cheng-Hung Wu,
  • Kuan-Chi Wang,
  • Yu-Yun Wang,
  • Chenming Hu,
  • Chun-Jung Su,
  • Tian-Li Wu

DOI
https://doi.org/10.3390/nano12030468
Journal volume & issue
Vol. 12, no. 3
p. 468

Abstract

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In this work, the ferroelectric characteristic of a 5 nm Hf0.5Zr0.5O2 (HZO) metal-ferroelectric-insulator-semiconductor (MFIS) device is enhanced through strained complementary metal oxide semiconductor (CMOS)-compatible TiN electrode engineering. Strained TiN top-layer electrodes with different nitrogen (N) concentrations are deposited by adjusting the sputtering process conditions. The TiN electrode with 18% N exhibits a compressive characteristic, which induces tensile stress in a 5 nm HZO film. A device with 18% N in TiN shows a higher remanent polarization (2Pr) and larger capacitance value than the compared sample, indicating that the strained TiN is promising for enhancing the ferroelectricity of sub-5 nm HZO devices.

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