Open Ceramics (Sep 2024)

Preparation and characterization of YAG microspheres doped with Eu2+/Eu3+ for broad band emission

  • Marzieh Ghadamyari,
  • Róbert Klement,
  • Hossein Ebrahim Hosseini,
  • Milan Parchovianský,
  • Jozef Kraxner,
  • Dušan Galusek,
  • Sathya Narayanasamy,
  • Erwin Hack,
  • Gurdial Blugan,
  • Monika Michálková

Journal volume & issue
Vol. 19
p. 100654

Abstract

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Achieving full-spectrum lighting is a major challenge for phosphor-converted light-emitting diodes (pc-LEDs), which are crucial for solid-state lighting. This study presents the synthesis of polycrystalline Eu-doped Y3Al5O12 (YAG) phosphors through a sol-gel method and flame synthesis process, leading to XRD amorphous microspheres. The amorphous nature of the microspheres allows the reduction of Eu3+ to Eu2+ at a significantly lower temperature (800 °C) than the reduction of crystalline samples described in the literature (1400 °C). The presence of Eu2+ in the YAG lattice was confirmed by X-ray photoelectron spectroscopy (XPS). The X-ray diffraction (XRD) of samples annealed in reducing atmosphere confirmed partial crystallization of pure YAG in all examined samples. The Eu-doped YAG phosphor embedded in residual glass microspheres exhibited a broadband emission spectrum over the wavelength range 450–800 nm peaking at 565 nm, corresponding to the 4f65d1→ 4f7 electron transition within the Eu2+ ions.

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