Measuring and Regression Modeling of Gas–Particle Partitioning of Atmospheric Oxidized Mercury at a Coastal Site in Shanghai

Abstract

Gas–particle partitioning between reactive gaseous mercury (RGM) and particle bound mercury (PBM) controls the fates of atmospheric oxidized mercury (namely reactive mercury, RM). We conducted a long-term observations of gaseous elemental mercury (GEM), RGM, PBM, and auxiliary parameters in Chongming Island, Shanghai, China, to understand the characteristics of speciated mercury and their gas–particle partitioning behaviors. The entire average abundances of GEM, RGM and PBM were 2.12 ± 0.94 ng/m3, 14.75 ± 9.94 pg/m3 and 21.81 ± 30.46 pg/m3, respectively. An observation data dependent empirical gas–particle partitioning relationship of partitioning coefficient and temperature log(1/KP) = −2692.20/T + 10.57 was obtained, and it varied in different season being by the temperature. To further evaluate the influences of temperature, particulate matter (PM), relative humidity on RGM and PBM partitioning process, the particulate fraction (φ = PBM/(PBM + RGM)) was used in this study. High φ values (φ > 0.8) mainly occurred at low temperature domain (<281 K), and high PM concentration enhanced this influence. In addition, high relative humidity shifts RGM from atmosphere partitioning to PBM in response to the diurnal valley φ values at 13:00–16:00 in the summer. Photochemical reactions were proposed to play important roles on partitioning processes between RGM and PBM. This study will benefit for the understanding of oxidized mercury fate and influencing factors in the complex atmospheric pollutants.

Keywords

• mercury
• gas–particle partition
• atmosphere
• empirical model